No, unless they're taking an additional irrational jump and claiming to be female. Which is a word defined in terms of biology, applicable to all organisms which reproduce sexually
'of or denoting the sex that can bear offspring or produce eggs, distinguished biologically by the production of gametes (ova) which can be fertilized by male gametes.'
TW are Male 'of or denoting the sex that produces gametes, especially spermatozoa, with which a female may be fertilized or inseminated to produce offspring.'
While it's possible to have treatments which render you infertile, humans (like all other mammals) cannot change sex. (As Dr Harrop presumably knows full well.)