yes Puff you can have French pedicure (or whatever the term is for toe nails??!!). it looks really nice and neat but would reccommend to have it done at a beauty salon till you get confident. nothing worse than french manicure done wrongly.
I've never had it done myself but quite a few of my friends were sporting it last year and it did look nice. mind you, these friends appear to spend most of their time at the hairdresser, beauty parlours, shopping, out at lunch etc etc!