I use one of the matt ones first all over - always a good idea with glittery eyeshadow as it helps them stick better. I used the palette last week to do a friends make up for a wedding, off the top of my head I think I used:
Liar - all over, just a light "wash" applied with the fatter end of the brush
Buzz - use the smaller end, and pat the flat of the brush on to the powder and apply it to the eyelid like that: don't rub or sweep the brush, just gently push it on to your eyelid with the flat side of the brush. I used this all over the eyelid i.e. on the bit that's directly on top of eyeball!
Mugshot - outer corner and crease of the eyelid
I then blend these quite well , I have another urban decay brush which has a longer end like this which I use for this.
I then used a little bit of darkside just on the very outside corner - literally patted a dot of it at the bottom outside corner of the eyelid, and blended.
I also used them very lightly under the eye almost as a liner which works really well.
Once this was all really well blended, I then used dust as a highlight on the inner corner of the eyelid, again patting it on.
I think the key is that these aren't shadows to sweep on.
I can try to do my eyes with it later and take a picture if you want?