I've just moved into a 2nd floor flat and the windows are a state. The frames and the air vents and the metal mechanism bit are just covered in deep grime, some bits are completely black or yellow (previous occupant was a chain smoker).
This is going to need more than a bit of vinegar so please keep home made natural ingredient type solutions to yourself.
I want to hear about chemicals, steamers, power jets, recommended professional services, that sort of thing.