My sinuses really hurt, above my jaw and behind my eyes 
I've had this before, and it comes on in the afternoon/evening, every day for a good long while (six weeks or so, at a guess). I used to get it as a student, then didn't have it for years, now I get it three or four times a year.
Because there's no sign of infection, I'm guessing it isn't sinusitis. What on earth could it be?