". . . we have a tiny house and no space apart from a sofa bed (my house when we met and we cant buy bigger as DH still paying for his exW house until DSD turns 18)"
He is living in YOUR house. Is it yours outright? Do you pay the rent? Mortgage? Lease? Does he pay rent/mortgage/lease? Is it still in your name? Are you letting him slide by, him not paying for his lodging, or does he pay for it? Are you underwriting his payments for child support by absorbing more household costs?
"Our joint income whilst not huge means that me and my DH are likely to have to fund quite a lot of her uni costs."
I suspect you are too generous and you are (rightfully) worried this will impact your son. It absolutely will unless you stand up.
You do not have to fund ANY of his daughter's uni costs. Pay attention; everything your husband earns and you earn in that marriage are joint assets, meaning both of you own them 50/50 unless you have a different agreement. Absent an agreement, it does not matter how much more he makes than you because you are married.
"I cant save up enough to cover his costs from my income and it just seems so unfair his life choices will be limited by me funding a child who is not biologically mine."
What do you mean from "your income?" WHAT? You have a joint income. Unless you don't? Is there an agreement to that effect?
It reads like he is not paying enough for his share of the household expenses. Makes him pay immediately. He does not get to send his daughter to college on your back. On your son's future. You two are 50/50. His daughter going to uni has zero bearing on his household obligations once she ages out of child support unless there is a court order.
If you own your home outright, he still has to pay the costs to live there, otherwise, you are (way) overpaying. Your son deserves that money. No wonder he can afford college for his daughter.
He cannot just give away as much marital money as it takes for his daughter to go to college. You are married, so it's 50/50. Relative income difference is not at work here unless you have a written agreement otherwise.
The money he was paying for his daughter's support all returns to the marriage. He wants to do this, he can, but not at the expense of your marital assets which are 50 percent. He can spend his own money from his 50% portion of marital assets after the joint household obligations have been met.
You should absolutely get advice from a family law specialist if you are co-mingling funds, and assuming his and your incomes are joint to the marriage.
If you want to send your son to uni then get to your feet; stand up for what is yours by right of marriage.