I'd be doing like a few other posters have said, putting it on the doorstep in a clear sandwich bag or something - with a note saying 'no thanks, and I don't want a catalogue bringing here again. Thank you...' And if it did come again, then I would bin it. Not my problem if it comes out of their profits. I haven't asked for it, have I?
I used to absolutely love Avon in the 70s, 80s and 90s. (and for a few years of the 00s/noughties. (Well, my mum had it in the 70s as I was a child, but I used to order bits from it and use my pocket money!)
For a good 7-8 years in the 00s/noughties, I had an Avon lady who was incredibly reliable. She had about 150 customers and they all loved her. But she stopped in 2009. Since then, I've experienced (in 3 different areas) 6 different Avon ladies who've just been useless and have let me down over and over.
I don't know if they can't get enough customers, or if they're just too lazy - and can't be arsed to keep coming out to post the catalogues, then come back to pick them back up, then come back to bring the stuff you order, then come back to bring it again, if you haven't got the money at the time.
But 6 different ones who were shit/unreliable?! (From 2009 onwards!) Crazy!
I did actually order from them all too. A couple of them went maybe 4 to 6 months and then stopped, a couple more just did 2 to 4 orders and then stopped, and the last two just put the catalogue through the door and never came back! (The sixth one was 2019.)
So when a SEVENTH one put a catalogue through my letterbox last summer (2023,) I just stuck it back on the doorstep and left it. (No note, just didn't order anything.) She came back to take it after a few days. 4 weeks later she dropped another one off. I put a note in this time saying 'no thanks. And please don't deliver the catalogue again because I'm not interested thanks.'
She never came back!!! After a couple of months I binned the catalogue. Never saw her again, ever.
I got so fed up and will never engage with/order from an 'Avon Lady' again, because they are so unreliable ...