@TheYorkshirePudding Ahhh! whoops! That's a shame there isn't a breastfeeding group closer to you, as its really good having someone to actually see your babies latch and help with positions etc. I didn't have any family support network really either going into DD, but it does work out, and you pick things up. I think just remember babies are really forgiving whilst you're figuring it all out!
The Nappy Lady is a great place to start. There is a good questionnaire that looks at what's important to you (e.g. ease of use, how quickly nappies dry etc) https://www.thenappylady.co.uk/nappy-advice-questionnaire.html which is a great place to start.
Its worth considering if you want to cloth from newborn, or not. Bambino Mio's and most other BTP (birth-to-potty) nappies DO NOT fit at birth (unless you have a really really big baby!!!). The nappy lady website as some really honest description of what weights the nappy is actually likely to cover. BUT saying that, Bambino Mio have updated their design looking at the link you shared (we have some Bambino Mio's but they are an older design, and this new design looks better!)
If you're thinking of going cloth, wait until cloth nappy week (which is the 22-28th April) to buy if you can, as you will get much better deals. You can also get good deals on second-hand nappies (save the planet twice). There are lots of facebook groups for buying/selling but also support and queries in general for using cloth nappies.
We bought some pocket nappies (where you insert an absorbent layer into a waterproof outer) for the newborn stag. But actually, what worked out the best financially and we ended up preferring were using muslinz muslins folded up with a cover/wrap - this kind of style is known as a 2-part system - as an absorbent layer with a separate waterproof layer. So we got 2 packs of these (different designs but same thing) https://www.thenappylady.co.uk/flat-nappies-prefolds/muslins-muslinz.html and some of these wraps in a small https://www.thenappylady.co.uk/mother-ease/mother-ease-velcro-fastening-rikki-wraps.html
You then fold the muslins (there are lots of folds you can do and online demonstrations) and secure with a nappy-nippa (think cloth pin with no pins, it just holds it in place) and put the wrap around it. Each wrap can withstand several changes (you don't change the wrap at every nappy change if its just wet). The muslins dry really, really quickly and can throw in the tumble drier, and the wraps again dry really quickly as they are basically just plastic. Its means you only need to keep a small stash if you're washing every other day, as things dry quickly. The bambino mio's I have are an older style that is AIO (all in one - i.e. the absorbent layer and waterproof layer are physically attached and cant be separated for washing) but it looks from the link you shared that this new 'revolutionary' style is now a pocket nappy (where you insert an absorbent layer that is not attached to the waterproof layer)
We didn't use cloth overnight when she was a newborn, as its just more fiddly doing cloth nappies at night when you want to keep changes quick, so we used disposables overnight for awhile. We didn't start doing over-night clothing either until she stopped pooing over night. If you want to not have to change the nappy for 12 hours overnight, you will likely eventually need something more absorbent than the Bambino Mio. We got some of these, again with separate waterproof wrap for overnight https://www.thenappylady.co.uk/best-sellers/bamboozle-stretch-stretchies-by-totsbots.html
I think with cloth many people think its all or nothing - we've very much found that we've used a combination of reusable and disposable nappies for different occasions. There are sometimes when life just gets a bit overwhelming to be washing a load of nappies, so we took breaks from cloth along the way.
Some people really like the nappy libraries, where you can hire a cloth nappy kit and see whether its for you before buying. Its also a good way of hiring nappies for the newborn stage without buying, and seeing what you like before buying BTP size nappies when baby is bigger