Sure. Germany, France, the Netherlands, Cyprus, Greece, Luxembourg, Denmark, Finland, Czechia, Hungary, Estonia, Slovakia, Switzerland, Norway, Iceland and Lichtenstein. All in 2024 used the Dublin Convention to return more people than they accepted under the same rules.
It wasn't designed as a deterrent to seeking asylum per se, it was designed to stop people from "shopping" for asylum by making repeat requests until they found a country that accepted them. And it has been extremely successful in doing that.