I’m a LP and there are options available.
In your position (town 45mins away, you like children, considering a child dev degree), I would encourage you to either pursue the child dev degree or else sign on with a local adult education centre and do a course to be a TA.
Other school hour friendly jobs include becoming a childminder; working in a restaurant/pub doing the lunchtime shift 10-2 or else finding an office job that you can leave in time to pick the kids up.
I’ve been really lucky with the firm that I work at that they’ve been incredibly flexible over the years as to what hours I work to be able to collect my son from school.
(Sorry if I’m teaching granny to suck it eggs) Do not, under any circumstances, consider MLM as it’s a scam and you will not make any money, no matter what the person recruiting you may say. There’s a long running anti-MLM thread here under Money Matters and also a page on FB called Anti MLM Police that’s worth a look if you are considering it. This includes Usborne Books, Body Shop and Forever Living etc.
As you say you like children, best bet is to ask the school where your DC attend to come in to have the children read to you, and then ask if you could volunteer there while undertaking your TA training.