i have tried to give furniture away on a council-run initative. Donate goods going to the needy.
One wardrobe was clean and dry, just old fashioned and they said they couldn't take it!
Another was a small TV, no remote (pre-remotes really) and they wouldn't take that!
Even when your paying for them to take it away, even when it's clean and dry, and in full working order the council wouldn't take it... but we used it for years.
i've been poor (no washing machine, no TV, no fridge) and i can tell you i'm extremely grateful for every single piece of furniture in my house (most was given free or bought second-hand).