Leek Leek Leek Leek Leek. Did I mention Leek? Best secondary school by a country mile is Painsley Catholic College in Cheadle but because of that, Cheadle house prices are slightly inflated and to get into Painsley there's a pretty strict entrance criteria. The best after that on the league tables and from local knowledge would be either Westwood or Leek High, both located in Leek.
Leek house prices are awesome, bought my first house there aged 23 for £93k, lovely little 2 bed end terrace with incredible views. The town is gorgeous too, tons of architecture and friendly as anywhere. Awesome pubs too and a very hot live music scene. There's a couple of good restaurants in the town centre but if you're wanting something a bit more lavish there's Macclesfield about 25 mins away, Stoke On Trent 20 mins away and Ashborne 30 mins away.
It's perched right on the edge of the Peak District so you've got The Roaches, Ladderage Country Park, Birchall, Leek Canal path, Rudyard, Tittisworth Reservoir, Brough Park etc etc etc all within about 10 minutes drive and depending where you are in town, most within walking distance.
The commute to Manchester for shopping would probably be a drive to Macclesfield train station and a train into Manchester for the day. I do this regularly because it's cheap as chips and a grand day out!
Living in the country, for me is the norm as i grew up in a small village, but my life now consists of weekends spend up to my eyeballs in mud while I take the dogs out up the canal path. It's a 4 mile walk and 4 miles back with a pub half way so in the summer a cider in the sun is very welcome! In the winder it's a pot of tea and soup and a sarnie 
I commute an hour to work (I work in Stafford) but it's not a difficult trip. A car in Leek is a must. They are building a train station in the next few years but there isn't one currently.
All in all it's a lovely life in the Peaks! 