DS has a single booking for a 3-leg flight via Booking.com. The first leg is with Vietnam Airlines and legs 2/3 are with Qatar Airways. Each leg has a separate flight number.
I'm concerned about Booking.com's poor Trustpilot reviews for flight bookings. The Booking.com T&C's are generic for all of their services and say changes/cancellations need to be arranged via the "service provider". In this case, would the service provider be the two different airlines? If there is an intermediate service provider then it isn't stated on the booking, but I've read that Booking.com do partner with Etraveli Group and GoToGate for flight bookings.