Just curious. I was reading an article on solar shading and was surprised it doesn't mention good old fashioned limewash, or the modern equivalent - chalk paint.
I've got a garage full of Annie Sloan, which I already use on a bathroom window to obscure it. A very quick bit of research says painting the exterior of my south facing French windows with chalk paint would cut absorbed heat by up to 90% compared to 40-60% for closing the curtains, and would wash off at the weekend.
Obviously I would recommend it as a solution for people in upper story flats or anything, but have I hit on a genuinely affordable and useful idea? How to shade your home