This might help. I'm not very good at run-throughs. Even though you hate iplayer, its still worth watching!
Rev Adam Smallbone has moved from a rural parish to inner city church, with his wife, who hates to conform to being "just" the vicar's wife, and is a solicitor. He has Reader, Nigel, who is very competitive and slightly anal and pedantic, there is a rampant cassock-chaser in his congregation, a strange character called Colin who likes to do things for church, but has no social graces, a pompous bossy archdeacon (archdemons they are called by my vicar!). Also a female head teacher, who it seems the vicar might have a crush on. This week's episode involved a church window getting broken, and the need to find funds for that, tied in with the local church school apparently about to get a good Ofsted, and so a bunch of unchurched parents turn up with their offspring to try to get them into the school. Think that covers it...