PS I would also add, it's important to limit solar gain as much as possible with passive systems which do not consume energy.
If you have a flat roof, solar-reflective paint helps.
If you have solar panels, leaving a gap between the roof and the panels helps with ventilation.
Awnings, especially over south-facing windows.
Or louvres: see and look up "smartlouvre" or "powell blinds"
Basically anything which is outside the room and can stop or reduce the sun from hitting your house, especially your windows. Internal blinds do not help as much because the sun has already entered your room, and they may just reflect it within the room. Oh, but you need planning permission to install external blinds in most cases.. Bureaucracy...
If you have skylights, eg in a kitchen extension or loft, put blackout blinds and replace them with openable ones. I have an openable skylight in the loft, it helps get the hot air out, and creates a modest but better than nothing ventilation with the other rooms