the second one doesn't look like a TRV to me.
Can you see any makers name on the head or valve?
Have a browse online looking for one to match.
start with
www.screwfix.com/c/heating-plumbing/thermostatic-radiator-valves/cat831012?cm_sp=managedredirect--plumbing--trv
www.wickes.co.uk/search?text=trv
and any chain like plumbase, toolstation, B&Q that has a depot local to you. Whoever fitted it probably bought local.
It may be an own-brand or a superseded model, but if you can identify it the maker may still have a valve with a compatible head.
Although you can buy extra heads as spares, it is usually cheaper to buy a complete new valve and use its head. Swapping heads needs no plumbing skills.
If you end up having to buy new valves, I recommend the RAS C2, and you may as well get new matching lockshield valves as a set.
Summer is the best time to work on heating systems,
Are you fond of plumbing?
Does your boiler have a pressure valve?