Hello everyone! My internet broke again. Sigh.
I come back and there is great news all round! Too I am absolutely delighted for you! I really am :)
And a new BFP Ninja Welcome!
Now breastfeeding that is something I know a little about 
I am a breastfeeding peer supporter, I am training to become a practitioner and I fed DD for two years.
If you have a CS you can have skin to skin in the theatre, you just need to ask.
The key things with skin to skin straight away is that it helps baby regulate their temperature. Your chest will act as a warming plate, and adjust its temperature so that your baby is the right temperature.
The skin to skin position, often with them more upright helps the mucous in their nose drain away. If you have them on their back (I.e standard cradle hold) then this can lead to feeding issues a couple of days later as they are snuffly, so the fluid draining off is really useful. If you can't do skin to skin then DP can, if he can't, then holding baby more upright will be a great help.
If for whatever reason breastfeeding is delayed try and hand express within the first 6 hours, don't panic also if baby doesn't latch right away there is actually a grace period with BF (40-50hrs), so plenty of skin to skin.
When introducing/getting it going there is nothing better than Biological Nurturing. I think there is some good vids on youtube. etc
Also, before you have baby, it is a really good idea to find out about support/groups in your area you can go to for help or meeting other bf mums. Children's centres are a good place to look. These groups can be invaluable, often HV can be a tad disappointing in their advice, so I would definitely advice finding people who actually know what they are talking about...
Sorry for the essay, I am quite passionate about BF not in judgemental you bottle fed your baby way, more that I want the mums who want to breastfeed to have the support they need. I feel very :( when a Mum hasn't had the support and is upset years later.
Also, you do know you don't have to see your HV? Do a couple of appointments and then forget about them, so much better than putting up with a mad one!
I hope my internet actually keeps working, it is like losing a limb when it keeps going!