@sparkleowl
Funnily enough my two adult dc are like yours 
Twice in the last two months we've had family/sibling birthdays and I've been asked to order what siblings want and they transfer the funds yet I'm still waiting.
That was the final straw this month after months of coffee out trips and everyone dispersing while I just pay the bill 
Sadly my parents are similar so I end up footing the bill both ends but I've stopped now.
The other night adult dc after I'd picked her up as her train was cancelled wanted to stop at a drive thru. She requested it,we got there,she then ordered and ordered for other dc (still a young teen)we got to the other side and she didn't even pull her card out just expected me to pay.
The realisation hit that im just too soft and being taken advantage of here.
Both my adult dc have a higher disposable income than me thanks to me finding things for them so of course they're going to expect it
So for the foreseeable I will no longer be doing it at all
I ordered some things on Amazon for my mum to aid her in recovering from a minor surgery.
She didn't even ask how much the items were or offered to re Imburse.
I just recently ended up footing the bill for a partial outbuilding fix they asked me to help sort out and I kick myself because they know full well I just let it go it's so frustrating.
I recently gifted them some money to treat themselves to a couple of meals out and they just seemed not appreciative or grateful and yet my useless sibling took a bunch of shop flowers down the other day and it's all she went on ablout even though I'd been and bought groceries to make things easier after the surgery as well as a bouquet of flowers.
Im going to have to get as tight as the kids and parents I think.
Im not funding them anymore