Line the two numbers up in a column making sure the decimals are on top of each other, add a zero to the 0.6 like so.
0.60
6.09
To figure out the largest you start from the left hand side and check each column for the highest number.
So if you had 5.67 and 5.98
5.67
5.98
Both are 5. something so first column doesn't help, look at tenths column one is 6 one is 9 so the one with the 9 is the biggest.
Units are bigger than tenths. You could label the columns as well. ones/units, tenths, hundreths.
Hope that makes sense - was teaching my year 10s the same as well this week!