It does sound like you're having a stressful time at the moment 
My suggestions are:
Eat better - this doesn't have to mean puritanical and boring! Get in healthy food that you enjoy and you're more likely to eat it. I'm around the same size as you and losing weight at the moment and this week in my Tesco order I put soreen Christmas ginger mini loaves - less than 100 cals but still feel/taste like a wee treat
Lose weight (see above) - see above again! Check out the "LOSE IT" weight loss threads in weight loss chat on here. I've been on them since June when I started and I've lost 1 stone (just over) I've still a lot to lose but I'm very happy with progress so far and the other posters are lovely and positive and supportive. Everyone is losing weight the way that works for them - no judgment. I love it, loads of tips and ideas and recipes exchanged of course too.
Take better care of my skin
You say you feel too tired to do a routine at bedtime - so do it before bedtime, it's not the law! Do it an hour or so before when you're watching whatever you watch before heading to bed?
Be more organised
With little twins I suspect you're already more organised than most! I live alone but am disabled and have various healthy issues but even when dd was still living at home/I was raising her I did the following:
Never leave a room empty handed - there's ALWAYS something that needs put in the room you're going to! This was one passed to me by my mum her place is always tidy and she can always find stuff which I struggled with at times and mentioned to her
Another tip of hers - if you lose something, when you find it put it in the 1st place you looked! (Unless that's impractical/unsafe in some way) THAT is where your brain thinks it is so put it there and you won't lose it again
I've always done a spreadsheet for my household budget inc an SOA (statement of affairs - ALL your income and outgoings inc those that only happen once a year like Xmas averaged out per calendar month), I do a 6 monthly forecast twice a year, takes a couple hours but it lets you see at a glance the rest of the time where you're at and if you can afford x
Spread household chores the big ones through the week - I was finding I was doing certain ones daily BUT others were getting neglected. Partly it was learning to accept that especially when I had a young child and was working full time the place was never going to be all tidy all at once. So I assign each room a day and I stick to that so eg Mondays kitchen, Tuesdays bedroom, Wednesdays bathroom...
I dunno how Tomm works but I'm guessing similar?
Stop spending money on coffee & cake (I’m spending a stupid amount on lattes & drinks when I go out with the girls as going out makes me feel better)
Back to having and sticking to a budget. When times were really hard for me and I really had to tighten my belt I did everything in cash except direct debits and withdrew - to the penny at the counter - how much I had that week and then when it was gone it was gone! Really focuses the mind when it's there in hard cash!
Stop buying chocolate - every time I fill the car up I come out with the chocolate bar as I convince myself it will perk me up & give me that boost they I need
See above
Food wise - carry a low cal treat with you, a cereal bar, mini soreen, small pack of low cal crisps from a multipack at home...
Gum is also good for these moments (sugar free)
Keep my car cleaner - it’s like a dustbin
To start as you mean to go on, and if you can afford it get a valet service! At least to give you a starting point
Reuse carrier bags as car bin bags for the twins and you to use. Get in the habit of clearing it daily
Keep my house cleaner/less clutter/try and find a “home” for everything
Again if you can afford, get someone in to help you Declutter, reorganise and have a "clear the decks" moment to start from.
Daily tidy up once twins in bed (you probably already do) pointless knackering yourself in the day doing it when they will simply undo your work!
I very rarely even look in the mirror anymore, I hardly ever buy clothes and then the ones that I do are just baggy shapeless cheap rubbish. I’m a size 16 but aware that I’m creeping up to the next size'
No matter what size you are, you are a person and you deserve to feel confident and well put together in your appearance - again if you can afford there are services to help you find your style and they give you guidance on what will suit your shape and size.
I used to do similar, buy cheap not very nice stuff partly through low self esteem, partly cos I was "going to" lose the weight soon and didn't want to "waste money" on larger clothes, partly to try and motivate myself into losing the weight
None of that works. What works is getting half decent clothes that fit and flatter and make you feel good about yourself - then you make better choices on eating etc too
I also agree on one thing at a time!
Tackle one thing this fortnight, crack that/make it a habit and then add something else - thats how I did the weight loss too. I started with simple changes that I barely noticed then added on every week or so something else
Good luck
Coffee and cake - you can choose lower cal options too.
If I'm in a coffee shop I usually have earl grey tea no milk with sweetener, choose the lowest cal option from the food/cake that's available
Costa and Starbucks I know have the cals on the price labels in the glass cabinets or on the packaging you could even check on their websites before you go.