I would do a list of pros and cons for each. What sort of commute? Driving door to door? Are there public transport alternatives? What impact would car problems cause? Can you take the train and read on the journey? There are lots of factors which can make a long commute more or less bearable.
The salary is clearly a lot more, but what about other benefits like pension, private health, whatever else? Are there any options for working from home occasionally - or regularly? Or for some flexible hours, starting earlier or later, or long lunch breaks?
What are the cultures like? What hours are expected? If they want your blood for the extra money, is it worth it?
You've got great feedback in your current place, but there's little chance of promotion - would that be important to you? Now you'be transformed your current place, will it be enough in a year or two, or will you need a new challenge?
Do you supervise people? Would you be expected to in the new job?
Some of these questions may be irrelevant, depending on the nature of the job, and some may be more or less important to you. Plus there are probably others I haven’t thought of.
If the money is the only thing in the new job''s favour, then as you don't need it, I wouldn't. But there must be more differences to justify over £20K difference in salary.
In any case, you don't really have to make a decision until you'very submitted an application, got through an interview and had a job offer. So think about what you really want, put in an application and use the interview to find out if the new job would fit what you want and need from a job. If they fail the interview, you can reject them if they offer you the job.