Freemasons.
A tiny handful of gentlemen's clubs in the West End of London.
Mammogram clinic (I've never seen a male member of staff in one)
Refuge for women escaping domestic violence (for now).
Until very recently, I'd have said:
Changing rooms in the lingerie department of big stores
Changing rooms marked as women's
Rape advisory service, women only session
Women's ward in a psychiatric unit
Swim sessions marked as women only
And so forth...
But increasingly it seems that a few transgender activists are testing the boundaries on all of the above.