I'm trying to remember this book
The protagonist is a female artist in the 17th/18th century.
I think she painted the pictures but her brother took the credit as it would have been unseemly for a woman to be a painter.
Sir Joshua Reynolds just popped into my head, perhaps he was a character.
The denouement involved the protagonist revealing herself to be the artist of a particular work by attacking the picture and scraping off the paint to reveal her signature below.
I listened to it as an audiobook 10 years ago so it's at least that old.
Many thanks