Surface tension of water?
Miniscule drops of water are between the pieces of ice forming the snow, acting like a glue.
Then, the molecules are attracted to each other, so they naturally form the shape which minimises the number of them that are not surrounded by others.
Hence, the Curved shape at the top of the pile.
But, obviously, there is a limit to how wide the curve can hold on top of a narrow fence top, therefore the sides of the curve (or imagine a ball stuck on a fence!!) fall off, leaving the straight edges.
Going bac to the whole surface tension ball stuck on fence thing, this is why it is curved, yet symetrical, as the fence is a certain width and the curve can only hold the same amount on each side, if that make ANY sense at all??
That is my TOTALLY uneducated guess, and I am probably wrong, but hey, I tried!!!