How controlling, nightmare type of relationship at any age,
reassure your DD, that adults have a very hard time recognising when they in a controlling relationships,
and that adults have a very hard time extracting themselves from them, she should understand it is no failing of hers that this is such a difficult situation to deal with,
I imagine if your daughter feels this way that others in the group also feel suffocated,
It can't go on, a relationship like this is far to draining to maintain and achieve the exam results she wants, you only have so much energy, and if this girl leeches all your daughter energy, she won't be able to give her best to her work,
If she is openly abusing your daughter, then by still accepting the relationship, your daughter, is advertising that she accepts abuse,
It's going to be horrible but she will have to reject this behaviour or it will increase,
Does your DD have the articulation to address her directly, would she be intimidated out of expressing her feelings to this girl? If she asked to meet for a coffee would she be heard?