Jeez, this brings back horrendous memories … been there and learnt hard way after trying to paint my house white. Never had this problem before when decorating in previous 35 years.
this seems to be happening more and more with paints.
they are reducing pigments especially white pigment ( titanium dioxide) and replacing with other substances with less opacity - it means you need so much more paint to cover with same level of opacity
add to that almost all all paints are now water based and not solvent based - they take longer to dry, and are more easily absorbed into substrate ( what’s underneath)
So what happens is that you put first coat on, applying more than you should probably and then not waiting to dry. You then apply another coat and it doesn’t adhere to that first coat properly(the substrate in this case ) , moisture and air get underneath the layers and it start to bubble. As it dries it blisters and starts to take the other layer off too in worst case.
sometimes it can happen because the substrate is not properly prepared - a layer of grease will build up over years, or even just fine dust , or worse case the wall is slightly damp - all these will stop even first coat adhere it to the substrate ( old paint in this case)
Even if you do get it to dry , over next years it will blister and come off
so, it’s about preparation : always wash your walls thoroughly first with something like sugar soap and then dry thoroughly . If you’ve a lot of marks, or dark colour to cover use a primer coat first .
then apply paint thinly- if you’re going to use white or pal colour you’ll need a lot of coats, but avoid applying thickly . Apply thin. Allow each layer to dry thoroughly.
The on,y way to fix is, sadly, sole destroying.
leave it to dry thoroughly.
sAmd it down all over to remove paint or use a paint stripper. Take it back to its substrate
wash walls thoroughly - using something like sugar soap
leave to dry for a few days
apply a base coat if needs if walls are patchy or uneven - leave for 36 hours min
then apply paint in thin coats , leaving to dry for at least 24 hours in between- it’s not just about touch dry, you want all the water out
Build colour up slowly
and have a good cry, swear etc while you at it 😭😭
it may help to buy really good quality paint - these should have higher pigmentation. Frankly I vowed never to buy crown trade white emulation again though and Valspar paints, but I think it happens with all of them given right conditions
Sorry, I don’t have better news .