Chemical injections do not cure sources of water.
The wet patch appears go be rising from floor level. I do not see airbricks on the external pics so it is probably a concrete floor. The covering should be removed to allow evaporation.
I see efflorescence, or possibly soap marks, on the wall, suggesting a drain leak.
There is a soil pipe, probably cast iron, against the wall.
The bottom of the wall has been painted black and had a plinth added. This is usually done to hide (it does not cure) damp.
The wall appears to be solid, not cavity.
When the house was built, it would have had a DPC, probably slate. Slate lasts at least 500 million years.
When the house was built the cast-iron soil pipe would have joined to salt-glazed brown clay pipe in the ground. This is pretty sure to have cracked at the first joint or elbow, and to have been leaking for about 80 years.
Look for the DPC. It will have been about 9 inches above ground level when the house was built. It may have been bridged by the plinth or later paving. You may be able to see it at or around a doorway.
Some closer pics of the wall, paving, plinth, doc, and external wall corresponding to the wet patch will help.
I have little doubt that the damp is due to a leak in the underground drain. It needs to be dug up and renewed. This is not a rare or complicated job, a well recommended local builder can do it.
I am told that there is an old house somewhere in the country that does not have broken drains, but I have never seen it.