As a sanity check, don't move anything yet, particularly not the thermostat. Your system may well have been set up with it where it is and it needs to be in a central space which is not subject to sources of heat that do NOT emanate from a radiator, hence the hall.
It should be on an internal wall, away from the radiator and outside doors and 1.5 metres high. The hall radiator should not have a thermostat, or the stat must be set at maximum.
Central heating is designed to heat different rooms to different temperatures, so all doors must be kept closed. The radiators will be sized to reflect the different temperatures required.
The hall will be designed to be about 17/18° maximum, this is done to minimize heat loss when the front door is opened, and so that the house doesn't feel like an oven when you come in. Other room's radiators will be sized accordingly.
Set the wallstat to 16° and all of the radiator thermostats to maximum and over a few days if needed, assess the comfort levels everywhere.
I suggest your target temps could be,
Bathrooms 23
Lounge 21
Dining Room 19/20
Bedrooms 17 to 19
Landing 17
Hall as per wall stat ;-)
Adjust the stat to achieve the best compromise for you, in older properties a setting of only 15° might be sufficient, but why do you need a warm hall?
Take your time over the above, aim to get things a bit too hot, then use the rad stats to bring down individual room temperatures.
A good reason for not having the stat in the lounge is that a few people, a large TV and a sound system constitute a heat source that isn't a radiator and could easily result in the lounge having to be uncomfortably hot in order to keep the rest of the house warm, particularly if it has a sunny aspect.