it's OK if you understand and are careful with it. The problem is that it is terminally sticky, and expands, and sets. So if it gets on wall, floor, carpet, clothes, skin, hair, eyeballs, fingernails, shoes, it will be hard work to get rid of. You need a crate of disposable gloves because as soon as a trace gets on a glove the glove becomes unusable. If you get it on the sole of your shoe it will tread into to carpets, floorboards, vinyl and concrete. You can get a chemical to make it disintegrate.
I got my best results by taping newspaper or clingfilm tightly to the floor, wall and window, and injecting it through a hole drilled in a cling-film-wrapped batten I had screwed over the cavity.
you have to fill incrementally, starting at the bottom, because it will swell and bulge out, and drip down the wall.
Once set, you can trim it with a breadknife..