If the kids rooms radiators are the cold ones, you don't need to touch them yet.
If you use UFH, it is usual to set the timer so that it turns on an hour or two at least before your radiators. You will find out in your house how long it takes for the heat to come through. In a concrete floor it can be a long time.
If you have some radiators that are cold and some that are hot, you can make a start by feeling the pipes under the hot radiators. The pipe at one end will get hot quicker when you put the heating on. This is the Flow pipe. The pipe at the other end is the Return pipe and should always be noticeably less hot. Write "F" and "R" on the pipes with a narrow marker pen, so it is not noticeable but you will be able to see it when you look. Next time you have ten minutes, feel the Return pipes on the hot radiators. Decide which of them is hottest. That is the one you should turn down first. If you are short of time, just do that one, and next day, feel it again to see if the Return is noticeably less hot than the Flow. If not, turn it down again. Once it is noticeably less hot, walk round and feel the other radiators, to find the one that now has the hottest Return, and turn that down. This will cause more heat to flow to the other radiators.
If you haven't got time to do them all in one day, at least do one. Once you have found how easy it is, you might do more. Remember only to turn them down a bit each time. The correct setting will be probably somewhere between half a turn and two turns from fully shut, which is surprisingly little. You only adjust the Lockshield valve, which is the one that (normally) has no knob on it, just a cover. The other end should be fully open.
Consider getting a door on that unused room. Heating an unused room is money down the drain.