if the radiators do'nt go warm when you run the hot tap, it is probably not the diverter valve (which can steal heat and send it to the radiators)
if running the bathtap brings hot water, but smaller flows don't, it might be the flow switch.
or you might have sludge and sediment blocking the heat exchanger, especially if you are in a hard-water area or the radiators are old.
if the radiators work it will not be the pump.
If you get any heat out of it at all, it is not under-pressure (this would stop it running) though it might be interesting to know what the pressure gauge reads, and what it moves to during and after running hot.
or it might be something I haven't thought of.
anyway, I don't see scope for a DIY adjustment, you need to ask around for a recommended local heating engineer. You might find an approved list on the maker's website, if you can't get a local recommendation. yellow pages, letterbox flyers, and recommendamender.com websites are not good sources.
Unfortunately this is the wrong time of year to look for a good engineer who is not rushed off his feet.