DH can't believe it, but I used to use it as my office and I know she isn't telling porkies (might be slightly wussy though).
Everything I find on the net that might help is for conservatories - this is an attic bedroom, with a perfectly good roof (had it done when we got the conversion). It's a nice big room and I could see it being great when she wants to play music or have friends over, which she has done. DD won't sleep in there though, so it's becoming a stately-home scale dressing room and she sleeps in the spare. Trouble is, I get really, really hot at night, so often go in the spare myself, so this is driving me nuts. Besides, the spare is good for Mum-in-law as right next to the bathroom and she's not very nimble.
Please - any ideas? I've got Velux blinds on the windows, plus I made curtains to go in front of those, but after that I'm baffled.