easy peasy
unless it is very old, it will be a fully pumped system. If either the hot water cylinder, or the room stat, calls for heat, and the timer is on, the stat opens a valve, the valve turns on the pump and the boiler.
If the pump is running, and the electrically-operated valve is worn out, or faulty, them some of the pressure from the pump will cause heat to go where it is not needed
These motorised valves have a brass part, with a rubber ball inside, which wears out, and an electic motor inside a metal or plastic head. On modern ones you can change the two parts separately. It is more trouble to change the brass part because you have to drain or bung the water, but it can be worth changing the head only if that is where the fault is.
The valve will usually be next to the pump and/or boiler and/or cylinder
usually like this
Start asking around for a well-recommended local plumber. As it does not involve opening up the boiler he does not need to be gas-safe registered, but can be.
It is a very common repair