I personally don't do a great deal after school with 5yo DD.
Monday - at after school until 4:20, then trampolinintg class 5-6, then home for dinner, reading, a bit of play and then story and bed.
Tuesday - at after school club until 5:30pm, then home for dinner, spelling practise, reading, a bit of play, stories and bed.
Wednesday - swimming after school until 5pm; then home for dinner, spelling practise, reading, a bit of play, stories and bed.
Thursday - is our free afternoon. She normally just comes home and play if not having a play date. She plays with her toys on her own. We fit in reading and dinner later on. She might watch some Tv or play on the computer, coolour, or whatever. I leave her to it to chill after school.
Friday - I collect a friend's DD from school and she and DD play at our place, having dinner together. I leave them to it again
I figure that DD just wants time out without anything structured once she is home.