My hubby was made redundant two years ago. The first thing we did was to contact the bank, the building society and our credit card companies to let them know the situation. They were all really brilliant and understanding - we worked out minimum payments and completed various forms which entitled us to insurance. In fact, Bank of Scotland allowed my hubby to pay a very small monthly amount for over a year - even though he managed to find alternative employment just a month after being redundant. I know many people are reluctant to let financial institutions know they cannot afford to pay them, fearing the worst, but it really is the best thing to do. As long as you keep them informed of what is going on they will bend over backwards to help you.
Another thing hubby did was to sign on as a temp at various recruitment agencies. It doesn't pay alot, but heck of alot more than £7.25 a week. One day he even drove a beer lorry to Suffolk! After being in a stressful situation with his previous job a change of scenery did him good and although there was the money worries, he was happier in himself.
The job centre in our next town runs a job club which hubby used as well. They give people the free use of email, fax etc to apply for jobs, they have all the job ads in various newspapers and someone was even able to help him amend his CV and put together something much better. Might be worth checking out if your town has similar facilities.
Once you get over the initial shock and depression of being made redundant there are plenty of things you can do to pull yourself up again. We managed to keep on our childminder, but we reduced hours, so hubby had a few hours free to write letters, attend interviews and do some work, but he also enjoyed extra time with our son.
He was very lucky that he found employment just a month later and on very similar wages, 3 months after that he found a new job where he has been ever since and is really happy.
Your brother has had 10 days to let it all sink in, now is time for action. I bet he'll have a new job before Easter (if not sooner) and will be able to put this all behind him. Good luck to him.