If your salary is 95k and you get a one off bonus of 7.5k making 102.5k I think that in addition to the 40% tax on it your personal allowance will reduce by £1250 adding a further £500 to the tax liability
have I got that right?
then if you were to put that 7500 into your SIPP and claim the extra 10%, will you still end up paying that extra £500?