It's the 'while we think what to do' short term aspect of the OP that makes PBs a possible option.
A S&S ISA is only for a long term investment. Especially at the moment while Trump plays Russian Roulette with the stock market - just my opinion.
With PBs, yes, you are essentially gambling with your potential interest. And the overall interest at their rate of % prize giving is not more than a high interest savings account. BUT you might get lucky, the winnings are tax free so that (if you get winnings) mitigates the lower % rate, and also, though it seems counter-logical, there is something complicated and mathematical to do with probability that increases your overall rate of winning the more bonds you have. Yes, obviously, the more you have the more bonds to win, but the rate increases more than this. Martin Lewis explained it in one of his Premium Bond 'luckometer' articles, and it is explained in the Novel 'The Curious Incident...' but I'm not one to explain it!
Tread carefully before putting money into your pension - it might be better to up the amount as salary sacrifice from your employer - or it might not!
It make NO financial sense to pay off your mortgage if you are borrowing at a low rate atm and could get a higher rate of interest in a high interest account or ISA. Also check for early exit fees / max overpayment.
OP - if you are a PYE tax payer you do an additional self assessment at the end of the tax year if your taxable interest has exceeded £1k that year. If it hasn't, do nothing. I think. The self assessment form has lots of helpful advice as you go through it, and the banks send you a Tax Certificate at the end of the tax year telling you how much interest you earned in that year. Again: Interest on ISAs and PB winnings do not count for tax!