I agree, Gilts are confusing!
For the individual gilts, you get back the original capital sum, plus interest (coupon payments along the way). The face value of a gilt is always 100. The 106 is what I believe is called the 'dirty' price, i.e. the price you pay to by the gilt on the secondary market. So you'd be paying more than the face value of the gilt in order to get just under 4 years' worth of interest payments (6% per year), plus 100 returned as capital when the gilt matures. This is because prevailing gilt yields for the term of the bond are currently around 4-4.5%, so what you get back should be around that amount, annualised. Meanwhile, the price of the gilt will move around, but if you hold to maturity you know exactly what you're getting back as capital and interest.
In some cases you'll see that the coupon payment is much lower than 6%, sometimes below 1%, because those gilts were issued at a time when interest rates (and gilt yields) were near zero. You can buy those for less than 100, so that, again, your returns come to the same as the current prevailing gilt yields. So you might get back, say, 5% as capital (the difference between, say, 95 and 100), and the rest as lower coupon payments. A lot of investors like low coupon gilts because any capital gain is tax free, while coupons are subject to income tax over your savings allowance. Other investors prefer higher coupons because they want the regular income.
There are gilt return calculators online which you may find helpful, and Investopedia provides a basic explanation of how gilts work.
There are also index-linked gilts, which return a fixed amount plus inflation, but these can behave very differently, so I don't recommend them if you are just starting out.
The reason a bond fund, like the Vanguard one, is at risk level 5 is because, unlike a single gilt, where you know exactly what return you are getting, the gilts held in a fund will be maturing at different times, meaning that the value of the units in the fund will fluctuate, and it isn't possible for an investor to sell out with any certainty of return. Bond funds fell very sharply a couple of years ago when interest rates starting going up. But anyone holding a gilt would have been fine, as long as they waited until it matured, when the full capital value would be returned.