Here's an example of how you could write them out, showing how certain things repeat (obviously you could do the ordering in lots of different but logical ways). I've here ordered them by how many blacks in the first half, and then with each of those, you have several ways to arrange the number of blacks in the second half).
bbbb wwww (four blacks in first group, and only one way to do this)
bbbw bwww (three blacks in first group, and there are 4 ways to do this)
bbbw wbww
bbbw wwbw
bbbw wwwb
bbwb bwww
bbwb wbww
bbwb wwbw
bbwb wwwb
bwbb bwww
bwbb wbww
bwbb wwbw
bwbb wwwb
wbbb bwww
wbbb wbww
wbbb wwbw
wbbb wwwb
bbww bbww (two blacks in first group, and there are six ways to do this)
bbww bwbw
bbww bwwb
bbww wbbw
bbww wbwb
bbww wwbb
bwbw bbww
bwbw bwbw
bwbw bwwb
bwbw wbbw
bwbw wbwb
bwbw wwbb
bwwb bbww
bwwb bwbw
bwwb bwwb
bwwb wbbw
bwwb wbwb
bwwb wwbb
wbbw bbww
wbbw bwbw
wbbw bwwb
wbbw wbbw
wbbw wbwb
wbbw wwbb
wbwb bbww
wbwb bwbw
wbwb bwwb
wbwb wbbw
wbwb wbwb
wbwb wwbb
wwbb bbww
wwbb bwbw
wwbb bwwb
wwbb wbbw
wwbb wbwb
wwbb wwbb
bwww bbbw (one black in first group, and there are 4 ways to do this)
bwww bbwb
bwww bwbb
bwww wbbb
wbww bbbw
wbww bbwb
wbww bwbb
wbww wbbb
wwbw bbbw
wwbw bbwb
wwbw bwbb
wwbw wbbb
wwwb bbbw
wwwb bbwb
wwwb bwbb
wwwb wbbb
wwww bbbb (no blacks in first group, and there is 1 way to do this)
You might recognise the numbers in each 'group' of combinations:
1, 4, 6, 4, 1 (pascal's triangle)