I am just starting out too, so would be interested to hear people's replies. At the moment, I try to start work with DS (12) at 10 am, after I have come back from taking DS2 to school. We usually start the day with reading. Then he does some Maths and then some Science. After lunch, we go for a short walk. One morning a week, I want to take him swimming. One afternoon a week, we are going to do a project (probably on Spain, where we're going on holiday - am hoping to cover a smattering of the language, plus history and culture). After school finishes, his best friend usually drops round and they play Minecraft together and chat.
I make it all sound very organised. In truth, this is simply an aim, not necessarily a reality. For instance, there are days when I'm not at home and DH is the adult in charge. On those days, DS does some BBC Bitesize stuff, reads and does his utmost to get back onto Minecraft at every opportunity. On days when I am trying to do Maths with him, he complains, whines and gets away at the earliest opportunity!
I have no idea if this routine will continue. From what I've read, a lot of people start out with a structure, but gradually relax into home ed and become more flexible. In my situation, DS1 is still registered at school, so he is getting schoolwork sent home, which means we are tied into the National Curriculum still.
How long have you been home educating?