Which devices are on more than off ?
I'm guessing that you don't leave games consoles on 24x7, but might switch TVs to 'standby', and so on.
I'd suggest changing the settings in (for example) your TVs and any TV-related kit (eg Sky ? box, which might be downloading 'anytime' programmes even if you never watch them and didn't even want to use it)... so for example choose a new wireless password, set it in some items each day (ie so they CANNOT connect until finally you change the p/w on the router) and see if the usage goes down one night.
Which ISP are you using? Some give more detail than others... Are you able to identify particular hours of high usage vs low usage?
Could any machine have a Torrent share running (aka Peer-to-Peer) ?
If you were spamming (sending out junk e-mail, because of a virus) then eventually your ISP might threaten to disconnect you.
Many desktops / laptops have network / system monitor software as standard, so you should be able to get some idea of data traffic (on Windows, there's the Task Manager, and my old iMac has Activity Monitor). When you are off to bed, you could ensure your systems 'sleep' (rather than just run a screen saver and blank the screen) so as to be sure your kit isn't causing the traffic.
No suggestions for how to monitor tablets and anything without a proper desktop / command line. It's where cables (with frantic LED flashing) have slight advantages over wireless when detecting what is/ is not working (!)
(I started in the early 80s with a network running on PCs on our dining room table and find wireless gives regular headaches when trying to fault find.)