Ok, it's a space for pots rather than an integral window box.
You need self watering pots that have a reservoir, otherwise you will be hanging out the window watering twice a day in summer. Lechuza are excellent, Elho also have a good choice with lots of fun colours, Wilko sell Clever Pots as a cheap alternative. Stewart also make budget versions (from Amazon or garden centres or DIY stores).
You don't want anything too tall or bushy as it will block the light. You could have a couple of Mediterranean quarter standard plants (like a lollipop shape) or cut into a spiral or pyramid at either end eg rosemary, bay, olive lavender, even holly. Box, hebe or Ilex crenata balls could look good too.
www.marksandspencer.com/bay-tree/p/flp60178573?extid=ps_ps-gpla_ggl_flowers_food__-UK-css-_&gclsrc=aw.ds&&gclid=Cj0KCQjwg7KJBhDyARIsAHrAXaE4reC3EMGtccniyb74WGO3h2gp0oxJ--yTyTTSdGQF8bQTbfWunfQaAvnZEALw_wcB&gclsrc=aw.ds
www.charellagardens.co.uk/buxus-sempervirens-ball-30cm-5-litre/?gclid=Cj0KCQjwg7KJBhDyARIsAHrAXaGC8hjVxrIjUbeUE0jBFEEHzhfekIOlRpCHFM5od605K5bhoeuv2RQaAlKYEALw_wcB
Geraniums/pelagoniums are the easiest, low maintenance Mediterranean window box plant. They can flower for about 9 months on a sheltered London balcony, they are drought resistant if you forget to water them and evergreen (have leaves all year round). You can get trailing and upright varieties. Salvias are good too but would need trimming every year. They have the advantage that the flowers are on long stems so you will see the flowers without the plant blocking the light.
www.fibrex.co.uk/collections/pelargoniums
www.norfolkherbs.co.uk/plant-type/salvias/
Look up how to lasagne plant bulbs so you get different flowers each month eg giant snowdrops (Jan), miniature irises, crocuses, early daffodils (Feb), then there is a huge choice after that. I would underplant with bulbs around the shrubs and then have some pots of bulbs with flowers on top (the bulbs will find their way into a gap).
If you go for something like geraniums, the bulbs will need to be the taller varieties. I would grow violas/pansies around shrubs on top of bulbs (Cool Wave can bloom all year round in London) or a creeping thyme (I love thyme lemonade, it really does smell like lemonade). You might not see them unless you are close to the window but they are better than a view of bare earth and will help keep out the weeds!
www.sarahraven.com/products/velvet-winter-windowbox-collection?gclid=Cj0KCQjwg7KJBhDyARIsAHrAXaGmd-P2VsF7Zr-UH5BHk9939-YKhuGaUFUaMj0CrYvbDgITVXHlscEaAoQNEALw_wcB&gclsrc=aw.ds
www.thompson-morgan.com/p/pansy-cool-wave-collection/WKC1064TM?source=google-prodex&gclid=Cj0KCQjwg7KJBhDyARIsAHrAXaHov1WFly3uIwSGt78E0ugQ7PzbzaBKr1lWiOrOshOWa6jwXJQQN0QaAogHEALw_wcB
www.norfolkherbs.co.uk/product/thyme-lemonade/
I also put aquarium gravel on top of my pots. It helps reduce weeds (which will be a pain to get rid of as you don't have easy access to the space) and slugs, and it looks neat.