Ok, I have had it a few times already. The recipe (Nigella Lawson's) is to melt the chocolate and butter, when the chocolate is cooler I add eggs with sugar; then the flour.
It has happened a few times that the mixture becomes kind of glossy and when it is baking I can see butter is on the top of the cake. When the cake is baked there is still butter, it is somehow becomes an oily brownie.
I think it could be because the chocolate and the butter were melted longer than it should be. I do not usually add eggs to the very hot chocolate. I leave the mixture to cool for about 10 min.
Has anyone experienced something like this before?