I'm not sure that anything is actually calorie neutral, but (green) veggies are pretty low calorie items anyway. Lots of people find a large salad with, eg. plenty of green leaves, radishes, celery, mushrooms (not officially a veg!), sliced peppers, a few olives, a handful of fresh herbs and a home-made vinaigrette dressing very filling, especially with a serving of protein (boiled eggs, piece of meat, tin of fish etc.).
Cooking, though, collapses plant cell walls, so cooked veg are much denser (so your whole bowl of fresh spinach becomes 2 spoons of wilted). Also, there's the added cooking fat that needs to be accounted for.
In my experience, it's always best to MFP everything at the beginning, until you find out what are your "almost-free" foods.