Because water is scarce. Bizarre I know when we live in such an apparently wet place. Simply put, the current calculations firstly work out how much the environment needs, then what is left is available for us to use. In the south and east, most of our supply is from groundwater which have to supply both human needs and the local river systems. The south and east of the country is also where rainfall is lowest, and population, and so demand is highest. In these areas there are rivers which, if you do the sums, don't have enough water in them to keep the environment happy. There are other rivers which, if those who are legally entitled to take water, took all of their quota, would also be in the same position.
The number of rivers that are 'in balance, is in fact not large, and the number where there is potentially water available which could use, is even smaller in number. Broadly speaking you would find these in the west, where, no surprise, it's wettest and populations are lower. But even there we can't afford to be casual.
That's all a bit of a generalisation, but you get the picture. And the reason we don't transport it is because it if we can help it is that it's really heavy stuff, and so energetically (and so also financially) very expensive stuff to move around. We do move water where needed (a bit), but there's a cost/benefit excercise that has to be carried out first to work out if it's a reasonable proposition.