Owl wireless energy monitor. You can tell if you've left something on standby.
One Click power cables - you turn off the PC and it turns off the power to all peripherals. Also works with the TV - you turn the TV off and it can turn off the DVD and Video, or with the amp and it turns off the tuner, CD player etc.
Not really an eco-gadget, but if you are an urban parent, car sharing clubs like the City Car Club are a great way to have occasional access to a car and not have the same kind of impact as owning one.
Expensive, but very good if you have a garden big enough, is a geothermal heat pump which makes a bit of a mess of your garden initially, but is v. low maintenance and a v. efficient way of generating free heat.
Condensing combi-boilers if you can't do the heat-pump thing.
I installed an electro-magnetic water conditioner after we had to replace a lot of scaled-up pipework - contrary to the hype, it doesn't stop scale altogether, but it certainly seems to be less of a problem now.
Not so much of a gadget, but getting your appliances serviced (including boilers, washing machines and dishwashers) can save a lot of energy.
Entirely personal view - from experience the following are utter rubbish:
Eco-balls
Soap-nuts
solar battery chargers
wind-up torches (except the LED ones)
Amazed to see Jennster - are we related?