If your husband works around or near the Uni, then I would really recommend living on the eastern side of town or over the borough in Wokingham - traffic through the town centre is awful and really best avoided. It can easily take 40 mins to get from Uni to Caversham during rush hour, in heavy slow traffic.
If east, you have the choice of Reading LA schools and also Wokingham LA schools - especially Wokingham secondaries: Bulmershe, 2 Maiden Erlegh schools (the Wokingham one has a better reputation than the one in Reading, but I've yet to meet a parent who is happy with the pastoral care... exam results are good though). Bulmershe and Maiden Erlegh in Wokingham both have sixth forms. You need to live well within catchment for either of these schools. Maiden Erlegh in Reading has no sixth form, they're new so only have year groups up to the current year 9. I believe they use a catchment area and feeder primary system.
If your sixth former is very academic, you could consider the grammar school sixth forms (Kendrick for girls, Reading School for boys) but they tend to only offer traditional A level subjects; they're both in the east side of town within walking distance of the town centre though.
Primaries in this area are a mixed bag, in Reading: Alfred Sutton, St John's, Redlands - I would avoid New Town. Wokingham: Aldryngton, St Peter's, Hawkedon, Loddon Valley.
Do you have an idea of a budget of you're looking to move / buy?