You will be losing most of the heat through uninsulated walls and single glazing.
The problem with kWh usage is not what it costs to get it up to temperature, but to keep it there.
We live in a 12 yo house but the thermostats are all on the wrong walls so they are constantly going on and off to try to get the temp to 19, even though we are highly insulated (where we are is very windy too).
At least 20% of my winter electric is turning the damn thermostats and TRVS on and off.
We used 2079 litres in oil last year = 21,500kwh. In winter oil is at least 10 litres a day = 103 kWh. Almost all of it is the stupid system turning on and off. Heating our water only uses 12 kWh a day.
You say you haven’t had the heating on and it keeps going up. What are the TRVs set to in each room? 1 is to stop pipes from freezing, 5 is like having your head in an oven. I have mine switched to 3 and when the OH is cold in the other side of the house and I am hot, I turn mine to 1.
I wonder if your boiler is still firing up to send a signal to TRVs to turn on and the action of it trying to turn on is costing all the money? Turn your TRVs to 1 and see what the £ looks like at the end of the day afterwards.
I am afraid the sort of house you describe loses a lot of heat, so 93 pd is what I would expect.