Just thought I should let people know who are in the same boat as I was. I emailed octopus asking what the prices per kw were for myself on economy 7.
It turns out if you pay two different rates for your electricity (IE economy 7) then the day rate goes up to 63p per kw, when the price cap set by ofgem is 34p per kw. And the night rate is 25p per kw.
So in short, unless you're using most of your electricity between 12pm and 7am. Then it will cost you far more on economy 7.
Apparently it says on their website that you can switch to the standard price cap 34p whenever you use electricity for free. So I would strongly advise doing this otherwise your bills will be even higher than they need to be unless you use a high percentage of your electric at night.